Hathaway made her bones as the star of syrupy Disney tween flicks, but she's grown up fast in movies like Brokeback Mountain, The Devil Wears Prada, and Becoming Jane.
The Brooklyn-born, Jersey-raised Hathaway made her TV debut in the short-lived Fox series Get Real while still in high school. Hathaway's big break came in 2001 when she starred in the saccharine Disney flick The Princess Diaries, which led to parts in a series of similar Disney films like Ella Enchanted and The Princess Diaries 2: Royal Engagement. She's since turned to more mature roles, earning billing as the next Julia Roberts or Audrey Hepburn and even garnered an Oscar nomination for her role in 2008's Rachel Getting Married. She's also taken a stab at blockbuster fare like Alice in Wonderland and 2012's The Dark Knight Rises. She has also graduated to the world of luxe endorsement deals with the likes of Lancôme and high-profile gigs like hosting the Oscars in 2011 with James Franco, but her hyperactive performance didn't go over so well.
A world class fag hag, Hathaway seems to be fond of bad boys: she dated nightlife impresario Scott Sartiano for a while and later attached herself to Italian playboy/con-artist Raffaello Follieri, who was indicted in June 2008 of allegedly swindled investors out of millions by posing as the Vatican's official real estate dealmaker. However, she decided to settle down with actor Adam Shulman when the pair became engaged in 2011. [Image via Getty]